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31.
以合成的g-C3N4纳米片和Ag/TiO2空心微球为原料,采用机械搅拌的方法构筑了g-C3N4/Ag/TiO2三元复合光催化剂。采用X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)、X射线光电子能谱(XPS)、紫外-可见光漫反射(UV-Vis DRS)和光致发光光谱(PL)对g-C3N4/Ag/TiO2进行了表征。研究表明,g-C3N4/Ag/TiO2是由Ag/TiO2微球和g-C3N4纳米片复合而成的。与TiO2相比,其可见光响应范围延长,光生载流子的分离速率加快。在室温下,用降解罗丹明B的反应考察了g-C3N4/Ag/TiO2的可见光催化活性。研究表明,光照180 min时,g-C3N4(0.5%)/Ag/TiO2显示了最高的光催化活性(91.9%),分别是TiO2和Ag/TiO2的7.5和1.8倍。光催化活性的提高与合理的异质结构建和Ag的导电性能有关。  相似文献   
32.
The problem of solving stochastic differential-algebraic equations (SDAEs) of index 1 with a scalar driving Wiener process is considered. Recently, the authors have proposed a class of stiffly accurate stochastic Runge–Kutta (SRK) methods that do not involve any pseudo-inverses or projectors for the numerical solution of the problem. Based on this class of approximation methods, classifications for the coefficients of stiffly accurate SRK methods attaining strong order 0.5 as well as strong order 1.0 are calculated. Further, the mean-square stability of the considered class of SRK methods is analyzed. As the main result, families of A-stable efficient order 0.5 and 1.0 stiffly accurate SRK methods with a minimal number of stages for SDEs as well as for SDAEs are presented.  相似文献   
33.
To solve the target covering problems in three-dimensional space, putting forward a deployment strategies of the target points innovatively, and referencing to the differential evolution (DE) algorithm to optimize the location coordinates of the sensor nodes to realize coverage of all the target points in 3-D surface with minimal sensor nodes. Firstly, building the three-dimensional perception model of sensor nodes, and putting forward to the blind area existing in the process of the sensor nodes sensing the target points in 3-D surface innovatively, then proving the feasibility of solving the target coverage problems in 3-D surface with DE algorithm theoretically, and reflecting the fault tolerance of the algorithm.  相似文献   
34.
A novel asymmetrical diarylethene with a (formyloxyethoxy)ethyl‐linked naphthalimide unit was synthesized, and its photochromic and fluorescence properties were systematically investigated in both solution and a poly(metyl methacrylate) film. The diarylethene showed significant photochromism and notable fluorescence switching properties upon irradiation with ultraviolet/visible light. Compared with the parent diarylethene, introduction of the naphthalimide moiety was effective to increase the molar absorption coefficient, the fluorescence quantum yield, and fluorescent modulation efficiency of the diarylethene. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
35.
The authors describe a voltammetric immunosensor with antibody immobilized on a glassy carbon electrode (GCE) modified with N-doped graphene (N-GS), electrodeposited gold nanoparticles (AuNPs) and chitosan (Chit). The preparation is simple and the thickness of the electrodeposited films can be well controlled. Due to the specific advantages of N-GS, AuNPs and Chit, the electrode has a large specific surface, improved conductivity, high stability. A new label-free immunosensor for the model antigen (alpha fetoprotein, AFP) detection was then designed by employing N-GS-AuNP-Chit as the antibody immobilization and signal amplification platform. Differential pulse voltammetry and electrochemical impedance spectroscopy were used for the characterization of the stepwise assembly process. Under the optimized conditions, at a typical working potential of +0.20 V (vs. SCE), and by using hexacyanoferrate as an electrochemical probe, the immunosensor has a detection limit as low as 1.6 pg mL?1 and a linear analytical range that extends from 5 pg mL?1 to 50 ng mL?1. AFP was quantified in spiked human serum samples with acceptable precision.
Graphical Abstract Schematic of sensitive and effective label-free electrochemical immunosensor for the detection of AFP based on N-GS-AuNP-Chit as signal amplification matrix.
  相似文献   
36.
合成了侧链带有咔唑的N-丙烯酰氧己基咔唑(MACZ),通过自由基聚合得到聚N-丙烯酰氧己基咔唑(PMACZ),在四氢呋喃含10%三氟化硼乙醚与四氟化硼四丁基胺的混合电解质溶液中,直接阳极氧化PMACZ获得自支撑交联网状的聚(聚N-丙烯酰氧己基咔唑)(PPMACZ)薄膜.PPMACZ薄膜具有良好的氧化还原性和热稳定性,电导率为1.34×10-5S·cm-1.1HNMR和红外光谱表明PMACZ二次聚合反应发生在咔唑单元的3,6位上,荧光光谱表明PPMACZ薄膜是一种良好的蓝色发光材料.  相似文献   
37.
采用量子化学的密度泛函B3LYP和二阶微扰MP2(full)方法对C4H4Y(Y=O,S,Se)与BX3(X=H,F,Cl)形成的电子授受型复合物进行了研究,所得18个复合物的构型包括BX3位于C=C双键上方的π-p作用型和B与O,S,Se直接作用的n-p作用型.体系C4H4Y-BH3以n-p作用型较为稳定,体系C4H4Y-BF3,C4H4Y-BCl3的π-p和n-p作用型复合物稳定性相当.对各复合物的几何构型、振动频率和自然键轨道分析表明,复合物的形成过程中均存在几何构型的改变、电荷的转移和振动频率的变化,它们的变化规律与复合物稳定性的变化规律基本一致,即按H,F,Cl的顺序依次降低.  相似文献   
38.
《Vibrational Spectroscopy》2007,45(2):331-342
Excitation profiles of different Raman bands of benzophenone molecule have been critically analysed. Structural and symmetry properties of the molecule in different electronic states have been investigated. The possibility of existence of an excited electronic state in the region bellow 200 nm has been explored. Calculations on isolated molecule in gas phase have been performed with the use of density functional theory to correlate the observed vibrational spectra. The time dependent density functional theory has used to determine the singlet excitation energies. The optimized structural parameters have also been computed.  相似文献   
39.
Juju Hu  Kehui Jia  Junshan Ma 《Optik》2011,122(23):2071-2074
We numerically investigate the synchronization performance of unidirectionally and bidirectionally coupled chaotic semiconductor lasers subject to multiple modulated time delays optical feedbacks. Moreover, by studying the autocorrelation function of the coherent feedback semiconductor laser output, we find that the signatures of time delays can be erased in systems incorporating modulated feedback time delays, which largely improve the system security. Finally, chaos masking switching (CMS) is utilized to examine the communication ability. Numerical results indicate that the messages could be successfully recovered both in unidirectionally and bidirectionally coupled lasers, which confirms the possibility of applying multiple modulated delay system in optical chaos secure communication.  相似文献   
40.
主要讨论Klein-Gordon-Schrdinger方程的Fourier拟谱辛格式,包括中点公式和Strmer/Verlet格式.首先构造一个哈密尔顿方程,针对此哈密尔顿方程,在空间方向用Fourier拟谱离散得到一个有限维的哈密尔顿系统,对此有限维系统在时间方向用Strmer/Verlet方法离散得到KGS方程的完全显式的辛格式.中点格式虽然是隐式的但效率也很高,且具有质量守恒律.数值实验表明,辛格式能够在长时间内很好地模拟各类孤立波.  相似文献   
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